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Production of Jatropha curcas L. Seed Oil DMC-Js-BioDs by Optimized Dimethyl Carbonate Using Potassium Hydroxide as Catalyst

Balaji M. Panchal, Hazem M. Kalaji

Abstract


Abstract

The use of Jatropha curcus L. seed oil as the feedstock for biodiesel (DMC-Js-BioDs) production has observed growing interest because it is a non-edible oil. In this study, the production of DMC-Js-BioDs from J. curcas seed oil with dimethyl carbonate (DMC) as the solvent was performed. The reaction was conducted in the presence of KOH as a catalyst to investigate the optimum conditions and study the effects of the variables on the reaction. These variables included seed oil to DMC molar ratios of 1:1 to 1:6, KOH catalyst concentrations of 0.5 to 2.5% on DMC basis, and 15 to 75 min reaction times at reflux temperature with agitation speeds of 25 to 175 rpm. The optimum conditions for DMC-Js-BioDs production were an oil to DMC molar ratio of 1:4, a catalyst concentration of 2.0% on DMC bases at reflux temperature and a reaction time of 60 min with 150 rpm agitation. The DMC-Js-BioDs yield under these optimum conditions was 96%, and all the measured properties of DMC-Js-BioDs met the specifications and international standards of ASTM D 6751-02. The experimental results showed that all the reaction variables in this research study had positive effects on the reaction.

 

Keywords: Alkali-catalyst, dimethyl carbonate, Jatropha curcus seed oil, magnesol powder, solvents

Cite this Article

Panchal Balaji M, Kalaji Hazem M. Production of of Jatropha curcas L. Seed Oil DMC-Js-BioDs by Optimized Dimethyl Carbonate Using Potassium Hydroxide as Catalyst. Journal of Alternate Energy Sources and Technologies. 2017; 8(2): 56–63p.


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DOI: https://doi.org/10.37591/joaest.v8i2.319

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