Open Access Open Access  Restricted Access Subscription or Fee Access

Halloysite nanotubes – A novel reinforcing material for future applications

Ravichandran G

Abstract


The distinctive nano materials such as nano powder, nano fluids, nano tubes, nano rods, nano particles, nano fibres and so forth are used in the field of nanotechnology. These nano materials are toxic in nature so not viewed as safe for people and for nature too. Halloysite nano tubes (HNT) are eco-friendly, naturally occurring cheaply available kaolinite group mineral. HNT incorporated materials have good in strength, thermal resistance and freely available, HNTs have a number of escalating applications such as cosmetics, drug delivery, fire retardant, structural, wear resistant, nano reactors, nano containers and soon. Due to large aspect ratio, low density, rich functionality and easily dispersed with any polymer, HNTs are used for high performance polymer composites and multi-functional nano composites. In this review, the exciting applications of HNT in different areas of research is discussed.


Keywords


Halloysite nano tubes; Kaolinite; low density; applications

Full Text:

PDF

References


J.H.Kirkman, “Possible structure of Holloysite disks and cylinders observed in some New Zealand rhyolitic tephras,” in Journal of Clay Minerals, 1977,Volume 12, pp. 199–216.

Yueping Ye, Haibin Chen, Jingshen Wu and Lin Ye, “High impact strength epoxy nanocomposites with natural nanotubes,” in Journal of Polymer, October2007,Volume 48, pp. 6426–6433.

E. Joussein, S. Petit, J. Churchman, B. Theng, D.Righi and B.Delvaux, “Halloysite clay minerals - a review,” in Journal of Clay Minerals, July 2005, Volume 40, pp. 383–426.

S.R. Levis and P.B. Deasy, “Characterisation of halloysite for use as a microtubular drug delivery system,” in International Journal of Pharmaceutics, 2002, Volume 243, pp. 125–134.

Lingyu Sun, Ronald F. Gibson, Faramarz Gordaninejad and Jonghwan Suhr, “Energy absorption capability of nanocomposites: A review,” in Journal of Composites Science and Technology, 2009, Volume 69, pp. 2392–2409.

Elshad Abdullayev, Ronald Price, Dmitry Shchukin, and Yuri Lvov, “Halloysite Tubes as Nanocontainers for Anticorrosion Coating with Benzotriazole,” in Journal of ACS Applied Materials & Interfaces, July 2009, Volume 1, pp. 1437–1443.

Pooria Pasbakhsh, G. Jock Churchman and John L. Keeling, “Characterisation of properties of various halloysites relevant to their use as nanotubes and microfibre fillers,” in Journal of Applied Clay Science, 2013, Volume 74, pp. 47–57.

Ulrich A. Handge, Katrin Hedicke-Hochstotter and Volker Altstadt, “Composites of polyamide 6 and silicate nanotubes of the mineral halloysite: Influence of molecular weight on thermal, mechanical and rheological properties,” in Journal of Polymer, 2010, Volume 51, pp. 2690–2699.

I.Deen, X.Pang and I.Zhitomirsky, “Electrophoretic deposition of composite chitosan–halloysite nanotube–hydroxyapatite films,” in Journal of Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2012, Volume 410, pp. 38–44.

R.T. De Silva, Pooria Pasbakhsh, K.L. Goh, Siang-Piao Chai and H. Ismail, “Physico-chemical characterisation of chitosan/halloysite composite membranes,” in Journal of Polymer Testing, 2013, Volume 32, pp. 265–271.

Pooria Pasbakhsh, H. Ismail, M.N. Ahmad Fauzi and A. Abu Bakar, “Influence of maleic anhydride grafted ethylene propylene diene monomer (MAH-g-EPDM) on the properties of EPDM nanocomposites reinforced by halloysite nanotubes,” in Journal of Polymer Testing, 2009, Volume 28, pp. 548–559.

Mingxian Liu, Yun Zhang and Changren Zhou, “Nanocomposites of halloysite and polylactide,” in Journal Applied Clay Science, 2013, Volume 75-76, pp. 52–59.

E. Huttunen-Saarivirtaa, G.V. Vaganovb, V.E. Yudinb, and J. Vuorinena, “Characterization and corrosion protection properties of epoxy powder coatings containing nanoclays,” in Journal of Progress in Organic Coatings, 2013, Volume 76, pp. 757–767.

Sandip Rooj, Amit Das and Gert Heinrich, “Tube-like natural halloysite/fluoroelastomer nanocomposites with simultaneous enhanced mechanical, dynamic mechanical and thermal properties,” in Journal of European Polymer Journal, 2011, Volume 47, pp. 1746–1755.

Youhong Tang, Shiqiang Deng, Lin Ye, Cheng Yang, Qiang Yuan, Jianing Zhang and Chengbi Zhao, “Effects of unfolded and intercalated halloysites on mechanical properties of halloysite–epoxy nanocomposites,” in Journal of Composites: Part A, 2011, Volume 42, pp. 345–354.

Shiqiang Deng, Lin Ye and Jianing, “Halloysite–epoxy nanocomposites with improved particle dispersion through ball mill homogenisation and chemical treatments,” in Journal of Composites Science and Technology, 2009, Volume 16, pp. 345–354.

B. Lecouvet, M. Sclavons, S. Bourbigot, J. Devaux and C. Bailly, “Water-assisted extrusion as a novel processing route to prepare polypropylene/halloysite nanotube nanocomposites: Structure and properties,” in Journal of Polymer, 2011, Volume 52, pp. 4284–4295.

Bo Yin and Minna Hakkarainen , “Core–shell nanoparticle–plasticizers for design of high-performance polymeric materials with improved stiffness and toughness,” in Journal of Materials chemistry, 2011, Volume 21, pp. 345–354.

Mingxian Liu, Baochun Guo, Mingliang Du, Xiaojia Cai and Demin Jia, “Properties of halloysite nanotube–epoxy resin hybrids and the interfacial reactions in the systems,” in Journal of Nano Technology, 2007, Volume 18, pp. 455703 –455711.

A. Alhuthali and I. M. Low, “Water absorption, mechanical, and thermal properties of halloysite nanotube reinforced vinyl-ester nanocomposites,” in Journal of Material Science, 2013, Volume 48, pp. 4260 –4273.

Xue-Gang Tang, Meng Hou, Jin Zou and Rowan Truss, “Poly (vinylidene fluoride)/Halloysite Nanotubes Nanocomposites: The Structures, Properties, and Tensile Fracture Behaviors,” in Journal of Applied Polymer Science, 2013, Volume 128, pp. 869 –878.

A G Anand Narayanan, Rajesh Babu and R. Vasanthakumari, “Studies on Halloysite Nanotubes (HNT) Natural Rubber Nanocomposites for Mechanical Thermal and Wear Properties,” in International Journal of Engineering Research & Technology, 2016, Volume 5, pp. 152 –156.

Nour F Attia, Mohamed A Hassan, Mohamed A Nour and Kurt E Geckeler, “Flame-retardant materials: synergistic effect of halloysite nanotubes on the flammability properties of acrylonitrile–butadiene–styrene composites,” in Journal of Polymer International, 2014, Volume 63, pp. 1168 –1173.

R. Nakamura, A. N. Netravali, A. B. Morgan, M. R. Nyden and J. W. Gilman, “Effect of halloysite nanotubes on mechanical properties and flammability of soy protein based green composites,” in Journal of Fire and Materials, 2013, Volume 37, pp. 75 –90.

Mingliang Du, Baochun Guo and Demin Jia, “Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene),” in European Polymer Journal, 2006, Volume 42, pp. 1362 –1369.

Peng Luo, Yafei Zhao, Bing Zhang, Jindun Liu, Yong Yang and Junfang Liu, “Study on the adsorption of Neutral Red from aqueous solution onto halloysite nanotubes” in Journal of Water Research, 2010, Volume 44, pp. 1489 –1497.

Suh Y. J., Kil D. S., Chung K. S., Abdullayev E., Lvov Y. M.and Mongayt D., “Natural Nanocontainer for the Controlled Delivery of Glycerol as a Moisturizing Agent,” in European Polymer Journal, 2011, Volume 11, pp. 661 –665.

Dmitry G. Shchukin, S. V. Lamaka , K. A. Yasakau , M. L. Zheludkevich , M. G. S. Ferreira , and H. Mohwald, “Active Anticorrosion Coatings with Halloysite Nanocontainers,” in Journal of Physical Chemistry, 2008, Volume 112, pp. 958 –964.

Jianjin Cao and Xianyong Hu, “Synthesis of Gold Nanoparticle Using Halloysites,” in Journal of Surface Science and Nanotechnology, 2009, Volume 7, pp. 813–815.

Kalappa Prashantha, Benoît Lecouvet, Michel Sclavons, Marie France Lacrampe and Patricia Krawczak, “Poly (lactic acid)/halloysite nanotubes nanocomposites: Structure, thermal, and mechanical properties as a function of halloysite treatment,” in Journal of Applied Polymer Science, 2013, Volume 128, pp. 1895–1903.

Mingxian Liu, Zhixin Jia, Fang Liu, Demin Jia and Baochun Guo “Tailoring the wettability of polypropylene surfaces with halloysite nanotubes,” in Journal of Colloid and Interface Science, 2010, Volume 350, pp. 186–193.

Wen You Zhou, Baochun Guo, Mingxian Liu, Ruijuan Liao, A. Bakr M. Rabie and Demin Jia “Poly (vinyl alcohol)/Halloysite nanotubes bionanocomposite films: Properties and in vitro osteoblasts and fibroblasts response,”in Journal of Biomedical Materials Research Part A, 2010, Volume 93A, pp. 1574–1588.

M. Liu, B. Guo, M. Du and D. Jia “Drying induced aggregation of halloysite nanotubes in polyvinyl alcohol/halloysite nanotubes solution and its effect on properties of composite film,”in Journal of Biomedical Materials Research Part A, 2007, Volume 88, pp. 391–395.

Kang-Suk Lee and Young-Wook Chang, “Thermal, mechanical, and rheological properties of poly (ε-caprolactone)/halloysite nanotube nanocomposites,”in Journal of Applied Polymer Science, 2013, Volume 128, pp. 2807–2816.

Ruiling Qi, Rui Guo, Mingwu Shen, Xueyan Cao, Leqiang Zhang, Jiajia Xu, Jianyong Yud and Xiangyang Shi,“Electrospun poly (lactic-co-glycolic acid)/halloysite nanotube composite nanofibers for drug encapsulation and sustained release, “in Journal of Materials Chemistry, 2010, Volume 20, pp. 10622–10629.

Mingliang Du, Baochun Guo and Demin Jia,“ Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene), “in European Polymer Journal, 2006, Volume 42, pp. 1362–1369.

R. R. Price, B. P. Gaber and Y. Lvov, “In-vitro release characteristics of tetracycline HCl, khellin and nicotinamide adenine dineculeotide from halloysite; a cylindrical mineral, “in Journal of Microencapsulation, 2001, Volume 18, pp. 713–722.

Yuri M. Lvov, Dmitry G. Shchukin, Helmuth Mohwald and Ronald R. Price, “Halloysite Clay Nanotubes for Controlled Release of Protective Agents, “in Journal of ACS Nano, 2001, Volume 2, pp. 814–820.

Hazim J. Haroosh, Yu Dong, Deeptangshu S. Chaudhary, Gordon D. Ingram and Shin-ichi Yusa, “Electrospun PLA: PCL composites embedded with unmodified and 3-aminopropyltriethoxysilane (ASP) modified halloysite nanotubes (HNT), “in Journal of Applied Physics A, 2013, Volume 110, pp. 433–442.

Ruiling Qi, Xueyan Cao, Mingwu Shen, Rui Guo, Jianyong Yu, and Xiangyang Shi “Biocompatibility of Electrospun Halloysite Nanotube-Doped Poly(Lactic-co-Glycolic Acid) Composite Nanofibers, “in Journal of Biomaterials Science, 2012, Volume 23, pp. 299–313.

Wen You Zhou, Baochun Guo,Mingxian Liu, Ruijuan Liao, A. Bakr M. Rabie and Demin Jia, “Poly (vinyl alcohol)/Halloysite nanotubes bionanocomposite films: Properties and in vitro osteoblasts and fibroblasts response, “in Journal of Biomedical Materials Research Part A, 2010, Volume 93A, pp. 1574–1587.

S.R. Levis and P.B. Deasy, “Characterisation of halloysite for use as a microtubular drug delivery system,” in International Journal of Pharmaceutics, 2002, Volume 243, pp. 125–134.

Johan Forsgren, Erik Jämstorp, Susanne Bredenberg, Hakan and Maria Stromme “A ceramic drug delivery vehicle for oral administration of highly potent opioids,” in International Journal of Pharmaceutics, 2010, Volume 99, pp. 219–226.

Elshad Abdullayev and Yuri Lvov,“Halloysite clay nanotubes as a ceramic “skeleton” for functional biopolymer composites with sustained drug release,” in Journal of Materials Chemistry B, 2013, Volume 1, pp. 2894–2903.

Yuri Lvov and Elshad Abdullayev,“ Functional polymer–clay nanotube composites with sustained release of chemical agents,” in Journal of Progress in Polymer Science, 2013, Volume 38, pp. 1690–1719.

Peng Liu and Mingfei Zhao, “Silver nanoparticle supported on halloysite nanotubes catalyzed reduction of 4-nitrophenol (4-NP),” in Journal of Applied Surface Science, 2009, Volume 255, pp. 3989–3993.

Wenbo Wei, Elshad Abdullayev, Anne Hollister, David Mills and Yuri M. Lvov, “Clay

nanotube/Poly(methyl methacrylate) Bone Cement Composites with Sustained Antibiotic Release,” in Journal of Macromolecular Materials and Engineering, 2012, Volume 297, pp. 645–653.

Luo, Bing-Hong, Hsu, Chung-En, Li, Jian-Hua, Zhao, Liang-Feng, Liu, Ming-Xian, Wang, Xiao-Ying, Zhou and Chang-Ren, “Nano-Composite of Poly (L-Lactide) and Halloysite Nanotubes Surface-Grafted with L-Lactide Oligomer under Microwave Irradiation,” in Journal of Biomedical Nanotechnology, 2013, Volume 9, pp. 649–658.

Mingxian Liu, Baochun Guo, Mingliang Du, Feng Chen and Demin Jia, “Halloysite nanotubes as a novel b-nucleating agent for isotactic polypropylene,” in Journal of Polymer, 2009, Volume 50, pp. 3022–3030.

Daria V. Andreeva and Dmitry G. Shchukin, “Smart self-repairing protective coatings,” in Journal of Polymer, 2008, Volume 11, pp. 24–30.

Andrew D. Hughes, Jocelyn R. Marshall, Eric Keller, John D. Powderly, Bryan T. Greene and Michael R. King, “Differential drug responses of circulating tumor cells within patient blood,” in Journal of Cancer Letters, 2014, Volume 352, pp. 28–35.

Mitchell M.J, Chen C.S, Ponmudi V, Hughes A.D and King M.R, “E-selectin liposomal and nanotube-targeted delivery of doxorubicin to circulating tumor cells,” in Journal of Controlled Release, 2009, Volume 160, pp. 609–617.

Andrew D. Hughes and Michael R. King, “Use of Naturally Occurring Halloysite Nanotubes for Enhanced Capture of Flowing Cells,” in Journal of Langmuir, 2010, Volume 26, pp. 12155–12164.

Michael J. Mitchell, Carlos A. Castellanos, and Michael R. King, “Nanostructured Surfaces to Target and Kill Circulating Tumor Cells While Repelling Leukocytes,” in Journal of Nanomaterials, 2012, Volume 14, pp. 5–14.


Refbacks

  • There are currently no refbacks.