Open Access Open Access  Restricted Access Subscription or Fee Access

Design of a Plant for the Production of Ammonia and Urea Using Aspen HYSYS

Ukpaka. C. P., Goodhead, T. O.,, Nweke, J

Abstract


The design of a plant for the production of 1800 MT/Day of ammonia and 1400 MT/Day of urea using aspen HYSYS was carried out in this work. Ammonia is produced through the Haber-Bosch process, where hydrogen and nitrogen react in the presence of a catalyst producing mixture containing ammonia while urea is produced by the reaction between ammonia and carbon IV oxide. In this work, aspen HYSYS, chemical engineering design software was used to design and perform material and energy balance around the plant. From the design analysis performed from the software, plant production capacity of 75,063 kg/hr. of ammonia and 58,343 kg/hr. of Urea was obtained. 7,677.6 kmole/hr. of methane gas, 19,194 kmol/hr. of steam and 3,584 kmol/hr. of air feeds was used to achieve the objective. The overall reaction is exothermic, and the primary reformer process is characterized by a low pressure. Cost estimation carried out showed that the total purchased cost of equipment was $9,881,055 fixed capital investment was $64,545,522, gross annual earning was $72,422,247, and net annual income was $54,316,685 rate of return was 38.85% and payback time was 2.5 years. Safety consideration for a smooth run of the ammonia-urea plant is also presented in this work. The design of a plant for the production of ammonia and urea using aspen HYSYS was well demonstrated in this research work, since the energy and the mass balance of each component was evaluated as presented in this research. Finally, the research demonstrates the usefulness of aspen HYSYS in the design of process plant for chemical base unit.


Keywords


Design, air reforming mixture, plug flow reactor, ammonia, urea, aspen HYSYS

Full Text:

PDF

References


Alhamdani YA, Hassim MH, Ng RTL, Hurme M. The estimation of fugitive gas emissions from hydrogen production by natural gas steam reforming. Int J Hydr Energy. 2017;42(14):9342–51. doi: 10.1016/j.ijhydene.2016.07.274.

Amjad U, Quintero CWM, Ercolino G, Italiano C, Vita A, Specchia S. Methane Steam Reforming on the Pt/CeO2 Catalyst: Effect of Daily Start-Up and ShutDown on Long-Term Stability of the Catalyst. Ind Eng Chem Res. 2019;58(36):16395–406. doi: 10.1021/acs.iecr.9b02436.

Bhattacharyya BC. Chemical Engineering Transactions. Chemical Equipment Design. 2003;69:385–90. doi: 10.3303/CET18669065.

Coulson J, Richardson F 2013. Particle technology and separation processes: chemical engineering Volume II. 5th ed. Main Ring Road. New Delhi, India: Elsevier. 2 34–567.

Davey W, Wurzei T, Lurgi AG; 2010. Method to produce urea from natural gas. The U.S. Patent n 767–788.

Edwin M, Abdulsalam S, Muhammed IM. Process simulation and optimization of crude oil stabilization scheme using aspen-HYSYS software. IJRTER. 2017;3(5):324–34. doi: 10.23883/IJRTER.2017.3230.MIIUW.

Hao Z, Gang R, Yipping, F. & Xiao yang, D. Integration Optimization of Production and Utilizing systems for Refinery wide planning. IFAC Papers online. 2014;24(29):959–64.

Joshi MV. Process Equipment Design. 3rd ed. Delhi, India: MacMillan India, 1996. pp. 193–207.

Khusaibi S, Rao LN. Design and production of hydrogen gas by steam methane reforming process. A theoretical approach. Int J Sci Technol Eng. 2016;3(1):472–6.

Muhammed T. Production of 250MTPD of ammonia from naphtha. Chem Eng J. 2009;24:1843–9.

Shreeve RN. Chemical process industries. 3rd ed, McGraw Hill Book. Oxford: Butterworth-Heinemann; 1967. p. 234–456.

Sinnott RK, Coulson JM, Richardson JF. Coulson & Richardson’s chemical engineering. Vol. 6. Oxford: Elsevier Butterworth-Heinemann; 2005. p. 233–398.

Temkin M, Pyzher. The kinetics of some industrial heterogeneous catalytic. New York: Palgrave Macmillan; 2004. p. 569–975.

Volvodic A, Medford AJ, et al. Exploring limit at low pressure, low temperature Haber Bosch process. Chem Eng J. 2014;81:147–52.

Ene PM, Ukpaka CP. Correlation model to monitor and predict the characteristics of homopolymerization of styrene in the case of isothermal and non-isothermal CSTR processes, Academic Editores. Acta Velit. 2016;3(1):128–50.


Refbacks

  • There are currently no refbacks.