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Kinetic Parameters of Corrosion Rate constant for Water-Based Plants for the Inhibition of Metal in Acidic Medium

Ukpaka. C. P., Izionwuru V. O, Chioma Onwubiko Hosanna

Abstract


Kinetic parameters of metal inhibition in acidic medium in the presence of water-based plant extracts to monitor corrosion rate characteristics was investigated in this research. The two water-based plasts used are pnematopteris pennigera (GF) and selaginella myosurus (SM) and the mild steel was immersed into the extracts and 1.0M of hydrochloride acid was added to monitor the rate of metal sample corrosion of the analytical grade (raw) HCl (87.3mls) in 100mls of plant extract samples. The variation in the corrosion rate constant K was monitored with the effect of temperature and the result obtained revealed increase in K value for A,B.C,H,J,K,L and N before sudden decrease after temperature range of 325K to 330K. The link which is the natural logarithm of corrosion rate in relationship to the reciprocal of temperature rate in relationship to the reciprocal of temperature reveals decrease and increase in the characteristics of the links. The efficiency of the inhibition upon the influence of time was monitored and the result obtained reveals initial increase in efficiency inhibition (Ei) with increase in time before sudden decrease and the effect of temperature demonstrates increase in inhibition efficiency IE. The inhibition characteristics in terms of the water-based plant extract has significantly revealed the usefulness of the plant extract in corrosion rate inhibition of metal in Hcl medium

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Adeniji E. S. & Bamigbola A. A. (2020). Comparative analyais of adsorption and corrosion inhibitive properties of ethanol extract of dialium, Open Journals of Physical Science 1(1), 16-25

Alan Miralrio & Araceli Espinoza Vázquez (2020). Plant Extracts as Green Corrosion Inhibitors for Different Metal Surfaces and Corrosive Media: A Review. Processes, 8, 942; DOI:10.3390/pr8080942

Ani J. U., Obi I. O., Kovo G. Akpomie, Samson I. Eze & Nwatu G. (2020). Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review. Journal of Natural Fibers, DOI: 10.1080/15440478.2020.1818345

Avci, G., & Keleş, Y. (2011). Aqueous extract of Acacia cyanophylla leaves as environmentally friendly inhibitor for mild steel corrosion in 1 M H2SO4 solution. Surface and Interface Analysis, 43, 1311–1317

Bhuvaneswari T. K., Jeyaprabha C. & Arulmathi P. (2020) Corrosion inhibition of mild steel in hydrochloric acid by leaves extract of Tephrosia purpurea. Journal of Adhesion Science and Technology, 34:22, 2424-2447, DOI: 10.1080/01694243.2020.1766395

Chukwure L. D, Ukpaka C. P., Dagde K. K. (2020). Inhibitor efficiency relative to H2SO4 medium of metals steel corrosion: Integration of plant extracts. Journal of Petroleum and Petrochemical Engineering, 6(4),13-20.

Chung Ill-Min, Kathirvel Kalaiselvi, Asokan Sasireka, Seung-Hyun Kim & Mayakrishnan Prabakaran (2019) Anticorrosive property of Spiraea Cantoniensisis extract as an eco-friendly inhibitor on mild steel surface in acid medium. Journal of Dispersion Science and Technology,

(9), 1326-1337. DOI: 10.1080/01932691.2018.1511435

Chung Ill-Min, Venkatesan Hemapriya, Seung-Hyun Kim, Kanchana Ponnusamy, Natarajan Arunadevi, Subramanian Chitra, Mayakrishnan Prabakaran & Mayakrishnan Gopiraman (2021) Liriope platyphylla extract as a green inhibitor for mild steel corrosion in sulfuric acid medium.

Chemical Engineering Communications, 208(1), 72-88. DOI: 10.1080/00986445.2019.169200

Dehghani A., Bahlakeh G, Ramezanzadeh B., Ramezanzadeh, M. (2019). Highly effective mild steel corrosion inhibition in 1.0 M HCl solution by novel green aqueous Mustard seed extract:

Experimental, electronic-scale DFT and atomic-scale MC/MD explorations. J. Mol. Liq., 293(11) 15-59

Dehghani Ali, Ghasem Bahlakeh, Bahram Ramezanzadeh (2019). A detailed electrochemical & theoretical exploration of the aqueous Chinese gooseberry fruit shell extract as a green and cheap corrosion inhibitor for mild steel in acidic solution. Journal of Molecular Liquids, 282: 366-384.

Deng S, Li X (2012). Inhibition by Ginkgo leaves extract of the corrosion of steel in HCl and H2SO4 solutions. Corrosion Science, 55:407–415

Derfouf Houaria, Yahia Harek, Lahcen Larabi, Wan Jeffrey Basirun & Magaji Ladan (2019). Corrosion inhibition activity of carbon steel in 1.0 M hydrochloric acid medium using Hammada scoparia extract: gravimetric and electrochemical study. Journal of Adhesion Science and

Technology, 33(8), 808-833. DOI: 10.1080/01694243.2018.1562321

Eno E. Ebenso, Indra Bahadur, M. A. Quraishicd (2018), An overview on plant extracts as environmentally sustainable and green corrosion inhibitors for metals and alloys in aggressive

corrosive media. Journal of Molecular Liquids, 266; 577-590

Fang Y., Baviththira Suganthan, Ramaraja P. Ramasamy (2019). Electrochemical characterization of aromatic corrosion inhibitors from plant extracts. Journal of Electro-analytical Chemistry, 840, 74-83

Foaud, N. & Ali, A. I. (2012). Inhibition of Aluminum Corrosion in Hydrochloric Acid Solution using Black Mulberry Extract. Journal of Materials and Environmental Sciences, 3(5), 917-924.

Gerengi Husnu, Agata Jazdzewska & Mine Kurtay (2015). A comprehensive evaluation of mimosa extract as a corrosion inhibitor on AA6060 alloy in acid rain solution: part I. Electrochemical AC methods. Journal of Adhesion Science and Technology, 29(1), 36-48. DOI:

1080/01694243.2014.973159

Giwa A. A., Adetunji A. T., Wewer F. (2020). Assessment of Negro pepper (Xylopia aetiopica) fruit extracts as corrosion inhibitors for mild carbon steel. Journal of Materials and Environmental Science, 11(7), 1100-1111

Karthiga N., Rajendran S., Prabhakar P., Joseph Rathish R. (2015). Corrosion inhibition by plant extracts-An overview. International Journal of Nano Corrosion Science and Engineering 2(4) 31-49

Kilo M., Rahal H. T., Mohammad H. El-Dakdouki & Abdel-Gaber A. M. (2020). Study of the corrosion and inhibition mechanism for carbon steel and zinc alloys by an eco-friendly inhibitor in acidic solution. Chemical Engineering Communications, DOI: 10.1080/00986445.2020.1811 239

Levenspiel Octave (2004). Chemical Reaction Engineering, 3rd edition, John Wiley & Son, Inc., New Delhi, India

Lyle, N. A & Schutt, I. E. (2010). Effect of CO2/H2S on Corrosion Behaviour of API 5L x 65 Carbon Steel in High CO2Environment. International Journal of Electro-Chemical Science, (4), 6512-6557.

Madu J.O., Ifeakachukwu C., Okorodudu U., Adams F. V., Joseph I. V. (2019). Corrosion Inhibition Efficiency of Terminalia Catappa Leaves Extracts on Stainless Steel in Hydrochloric Acid. Journal of Physics: Conference Series 1378 022092

Mayakrishnan Prabakaran, Seung-Hyun Kim,Asokan Sasireka,Kathirvel Kalaiselvi & Ill-Min Chung (2018). Polygonatum odaratum extract as an eco-friendly inhibitor for aluminum corrosion

in acidic medium Pages 2054-2069

Ogunleye O. O., Arinkoola A. O., Alagbe S. O., Agbede O. O., Omodele A. E., Morakinyo A. F., & Osho Y. A. (2020). Synthesis of green corrosion inhibitor for mild steel in acidic environment. Indian Chemical Engineer, 62(1), 52-66. DOI: 10.1080/00194506.2019.1625815

Orazem, M. E. (Ed.). (2014). Underground pipeline corrosion: Detection, analysis and prevention. Woodhead Publishing Limited Series in Metals and Surface Engineering: Number 63, Cambridge, UK

Raja, P. B. & Sethuraman, M. G. (2008). Natural Products as Corrosion Inhibitor for Metals in Corrosive Media: A Review. Materials Letters, 62(1), 113-116.

Sangeetha J., Nandakumar T., Vadivel M., Thinaharan C., Rani P., George L., & John Philip (2020). Corrosion inhibition of mild steel in 1.0 M HCl using Tamarindus indica extract: electrochemical, surface and spectroscopic studies. Journal of Adhesion Science and Technology,

(7), 713-743. DOI: 10.1080/01694243.2019.1681156

Sharma Deepak Kumar, Dave R. S., & Shah K. R., (2020). Proximate Analysis and Evolution of Energy Value from Leaves and Stem of Sword Fern: Nephrolepis exaltata. International Research Journal of Pure & Applied Chemistry, 21(17): 10-17, DOI: 10.9734/IRJPAC/202 0/v21i1730261

Singh Priyanka, Dheeraj Singh Chauhan, Kritika Srivastava, Vandana Srivastava & Quraishi M. A.

(2017). Expired atorvastatin drug as corrosion inhibitor for mild steel in hydrochloric acid solution. International Journal of Industrial Chemistry, 8, 363–372

Ueda, S. G. & Michaela, H. (2006). Fundamental Aspects of CO2 Metal Loss Corrosion. Paper Presented at The Corrosion 2006, San Diego, California. NACE 06112

Umoren Saviour A., Moses M. Solomon, Ime B. Obot & Rami K. Suleiman (2018). Comparative studies on the corrosion inhibition efficacy of ethanolic extracts of date palm leaves and seeds on carbon steel corrosion in 15% HCl solution. Journal of Adhesion Science and Technology, 32(17), 1934-1951. DOI: 10.1080/01694243.2018.1455797

Vasanthajothi R., Saratha R. & Krishnaveni K. (2021). Mild steel green inhibition by Hardwickia binata Roxb. leaves extract in acid medium. Journal of Adhesion Science and Technology, 35(3), 296-312. DOI: 10.1080/01694243.2020.1801248

Verma Dakeshwar Kumar & Fahmida Khan (2016) Green approach to corrosion inhibition of mild steel in hydrochloric acid medium using extract of spirogyra algae, Green Chemistry Letters and

Reviews, 9(1), 52-60. DOI: 10.1080/17518253.2015.1137976


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