Thin fluoropolymer coating on cotton textile to achieve hydrophobicity
Keywords:
Fluoropolymer, Admicellar polymerization, Contact angle.Abstract
We report a simple novel procedure to prepare hydrophobic cotton textiles by admicellar polymerization on the cotton surface. By in situ introducing fluoropolymer on cotton fibers to generate a dual-size surface roughness, followed by hydrophobization with a little amount of fluoromonomer Octafluoropentamethyl methacrylate (OFPM) with short time, normally hydrophilic cotton has been easily turned in to hydrophobic. Hydrophobic cotton textile exhibits a static water contact angle of 135° for a 10 µL droplet. When an octa fluoroalkyl chain is introduced to the cotton surface, the originally smooth surface changed immediately to rough a surface by which is the key factor for hydrophobicity like lotus leaves.
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