Open Access Open Access  Restricted Access Subscription or Fee Access

Application and Limitation of Metal Thermochemical Processing

Tanushka Singh Chauhan

Abstract


The technically intriguing and monetarily feasible technique for enhancing the surface layer of materials is surface engineering. The aim is to establish a vast scope of useable attributes that are separate from the core substrate, together with physical, chemical, electrical, electronic, magnetic, or mechanical, even though the material surface monitors the operational life throughout many implementations. The thermochemical intervention, a type of surface engineering, uses heat diffusion to incorporate non-metal or metal atoms into a surface of the material, changing the chemistry and microstructure of the surface. The methodology requires one or more contemporaneously active chemical elements in solid, liquid, or gaseous media. For the overwhelming bulk of thermochemical processes, the mechanism encompasses the collapse of solid, liquid, or gaseous species, the dispersion of gaseous molecules to generate nascent atoms, the assimilation of atoms, their dissemination into a metallic lattice, and interactions within the cellulose structure to modify or generate new phases. Surface diffusion is layered atop material volume changes, which for some treatments may also include phase shifts, which adds to the ambiguity. Industrial scale processes subject the complete segment to high temperatures; consequently, surface diffusion is superimposed on alteration within the material volume.

Full Text:

PDF

References


Pye D. Practical nitriding and ferritic nitrocarburizing. ASM international; 2003.

Georges J, inventor; Plasma Metal SA, assignee. Nitriding process and nitriding furnace therefor. United States patent US 5, 989, 363. 1999.

Yeh JW, Chen SK, Lin SJ, Gan JY, Chin TS, Shun TT, Tsau CH, Chang SY. Nanostructured high‐entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Advanced engineering materials. 2004; 6 (5): 299–303.

Yoshida M, Okumiya M, Ichiki R, Tekmen C, Khalifa W, Tsunekawa Y, Hara T. A novel method for the production of AlN film with high adhesion on Al substrate. Plasma Fusion Res. 2009;8.

Brady MP, Weisbrod K, Zawodzinski C, Paulauskas I, Buchanan RA, Walker LR. Assessment of thermal nitridation to protect metal bipolar plates in polymer electrolyte membrane fuel cells. Electrochemical and solid-state letters. 2002; 5 (11): A245.

Singaravelu S, Klopf JM, Krafft G, Kelley MJ. Laser nitriding of niobium for application to superconducting radio-frequency accelerator cavities. Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena.

; 29 (6): 061803.

Türk A, Ok O, Bindal C. Structural characterization of fluidized bed nitrided steels. Vacuum. 2005;80 (4): 332–42.

Korwin MJ, Morawski CD, Tymowski GJ, Liliental WK. Nitrided and Nitrocarburized Materials: Design. InEncyclopedia of Iron, Steel, and Their Alloys 2016 (pp. 2317–2356). CRC Press.

Dossett JL, Boyer HE. Practical heat treating. Asm International; 2006.

Czerwinski F. Thermochemical treatment of metals. Heat Treatment–Conventional and Novel Applications. 2012; 5: 73–112.

Bulfin B, Vieten J, Agrafiotis C, Roeb M, Sattler C. Applications and limitations of two step metal oxide thermochemical redox cycles; a review. Journal of Materials Chemistry A. 2017;5(36):18951-66.

Ricard A, Deschamps J, Godard JL, Falk L, Michel H. Nitrogen atoms in Ar N2 flowing microwave discharges for steel surface nitriding. Materials Science and Engineering: A. 1991; 139: 9–14.

Li CX, Bell T. Sliding wear properties of active screen plasma nitrided 316 austenitic stainless steel. Wear. 2004; 256 (11–12): 1144–52.

Schaaf P. Iron nitrides and laser nitriding of steel. hyperfine Interactions. 1998; 111 (1): 113–9


Refbacks

  • There are currently no refbacks.