Open Access Open Access  Restricted Access Subscription or Fee Access

Optical and Photocatalytic Activity Of Cmc Capped Zinc Selenide Nanoparticles Under UV Light Irradiation Using Congo Red Dye

T. Anantha Kumar, P. Mariselvi, G. Alagumuthu

Abstract


In this work, we report the, optical, structural morphology and photocatalytic activity of CMC capped zinc selenide nanoparticles, which have been synthesized by hydrothermal method. CMC is acted as capping agent. The nanoparticles were characterized using XRD, SEM with EDAX, AFM, TEM and UV-Vis absorption spectroscopy. The structural properties of nanoparticles have been characterized by X-ray diffraction (XRD) analysis. The XRD patterns show a hexagonal Wurtzite crystal structure. The surface morphology of the nanoparticles was analyzed by SEM and AFM analysis. Absorption spectra have been obtained using UV-Vis spectroscopy to find the optical band gap. In addition, photocatalytic degradation of congo red in aqueous solution was performed using CMC capped zinc selenide nanoparticles under the illumination of UV light.


Keywords


Nanoparticles, Congo red, Zinc selenide, Hydrothermal, CMC.

Full Text:

PDF

References


G.M. Dalphin and J.R. Chelikowsky, “Self-Purification in Semiconductor Nanocrystals,” Phys Rev Lett, Vol. 96, (22), 2006, pp. 22682-22684.

N. Chestnoy, R. Hull and L.E. Brus, “Higher excited electronic states in clusters of ZnSe, CdSe, and ZnS: Spin‐orbit, vibronic, and relaxation phenomena,” J Chem Phys, Vol. 85, 1996, pp. 2237 – 2242.

C.S. Hwang and I.H. Cho, “Characterization of the ZnSe/ZnS Core Shell Quantum Dots Synthesized at Various Temperature Conditions and the Water Soluble ZnSe/ZnS Quantum Dot,” Bull. Korean Chem Soc, Vol. 26, (11), 2005, pp. 1776-1782.

M.A. Malik, N. Revaprasadu and P. O' Brien, “Air-Stable Single-Source Precursors for the Synthesis of Chalcogenide Semiconductor Nanoparticles,” Chem Mater, Vol. 13, (3), 2001, pp. 913 - 920.

B. Ludolph, M.A. Malik, P.O. Berin and N. Revaprasadu, “Novel single molecule precursor routes for the direct synthesis of highly monodispersed quantum dots of cadmium or zinc sulfide or selenide,” Chem Commun, Vol. 17, 1998, pp. 1849 - 1850.

D.J. Norris, N. Yao, F.T. Charnock and T.A. Kennedy, “High-Quality Manganese-Doped ZnSe Nanocrystals,” Nano Lett, Vol. 1, (1), 2001, pp. 3 - 7.

M.A. Hines, P. Guyot Sionnest, “Bright UV-Blue Luminescent Colloidal ZnSe Nanocrystals,” J Phys Chem B, Vol. 102, (19), 1998, pp. 3655-3657.

H. Wang and F. Du, “Hydrothermal synthesis of ZnSe hollow microspheres,” Cryst Res Technol, Vol. 4, 2006, pp. 323–327.

A. Colli, S. Hofmann, A.C. Ferrari, C. Ducati, F. Martelli, S. Rubini, S. Cabrini, A. Franciosi and J. Robertson, “Lowtemperature synthesis of ZnSe nanowires and nanosaws by catalystassisted molecular-beam epitaxy,” Appl Phys Lett, Vol. 86, 2005, pp. 153103:1–3.

C. Jiang, W. Zhang, G. Zou, W. Yu and Y. Qian, “Synthesis and characterization of ZnSe hollow nanospheres via a hydrothermalroute,” Nanotechnology, Vol. 16,(4), 2005, pp. 551–554.

B. Pejova and I. Grozdanov, “Three-dimensional confinement effects in semiconducting zinc selenide quantum dots deposited in thin-film form,” Mater Chem Phys, Vol. 90, (1), 2005, pp. 35-46.

L.E. Brus, “A simple model for the ionization potential, electron affinity, and aqueous redox potentials of small semiconductor crystallites,” J Chem Phys, Vol. 79, (11), 1983, pp. 5566-5571.

W.Z. Wang, Y. Geng, P. Yan, F.Y. Liu, Y. Xie and Y.T. Qian, “A Novel Mild Route to Nanocrystalline Selenides at Room Temperature,” J Am Chem Soc, Vol. 121, (16), 1999, pp. 4062-4063.

M. Nirmal and L. Brus, “Luminescence Photophysics in Semiconductor Nanocrystals,” Acc Chem Res, Vol. 32, (5), 1999, pp. 407-414.

C. Bruda, S. Link, M. Mohamed and M. El-Sayed, “The Relaxation Pathways of CdSe Nanoparticles Monitored with Femtosecond Time-Resolution from the Visible to the IR: Assignment of the Transient Features by Carrier Quenching,” J Phys Chem B, Vol. 105,(49), 2001, pp. 12286-12292.

G. Alagumuthu, T. Anantha Kumar, “Synthesis and Characterization of Different Polymer Capped Zinc Selenide Nanoparticles by Hydrothermal Method,” International Journal of Advanced Scientific and Technical Research, Vol. 4, (6), 2014, pp. 182-193.

Rahdar, A 2013, ‘Study of different capping agent effect on the structural and optical properties of Mn doped ZnS nanostructures’, World Applied Programming, vol. 3, no. 2, pp. 56-60.

Archana, J Navaneethan, M Ponnusamy, S Hayakawa, Y & Muthamizhchelvan, C 2009, ‘Optical, structural and surface morphological studies of bean-like triethylaminecapped zinc selenide nanostructures’, Materials Letters, vol. 63, no. 22, pp. 1931–1934.

Oluwafemi, OS & Adeyemi, OO 2010, ‘One-pot room temperature synthesis of biopolymer-capped ZnSe nanoparticles’, Materials Letters, vol. 64, no. 21, pp. 2310–2313.

Yadav, K Dwivedi, Y & Jaggi, N 2015, ‘Effect of annealing temperature on the structural and optical properties of ZnSe nanoparticles’, Journal of Materials Science: Materials in Electronics, vol. 26, no. 4, pp. 2198-2204.

Nabiyounil, G Sahraei, R Toghiany, M Majles, M & Hedayati, K 2011, ‘Preparation and Characterization of Nano-Structured ZnS thin films Grown on Glass and N-type Si Substrates using a New Chemical Bath Deposition Technique, Reviews on Advanced Materials Science, vol. 27, pp. 52-57.

Wei, QL, Kang, SZ & Mu, J 2004, “Green” synthesis of starch capped CdS nanoparticles’, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 247, no. 1-3, pp. 125-127.

Lee, SM Cho, SN & Cheon, JW 2003, ‘Anisotropic Shape Control of Colloidal Inorganic Nanocrystals’, Advanced Materials, vol. 15, no. 5, pp. 441- 444.

Lee, SM Jun, YW Cho, SN & Cheon, JW 2002, Single-Crystalline Star-Shaped Nanocrystals and Their Evolution: Programming the Geometry of Nano-Building Blocks’, Journal of American Chemical Society, vol. 124, no. 38, pp. 11244-11245.

Sharma, M & Tripathi, SK 2012, ‘Preparation and nonlinear characterization of zinc selenide nanoparticles embedded in polymer matrix’, Journal of physics and chemistry of solids, vol. 73, no. 9, pp. 1075-1081.

Fujishima, A & Honda, K 1972, ‘Electrochemical photolysis of water at a semiconductor electrode’, Nature, vol. 238, no. 5358, pp. 37-38.

Kudo, A & Miseki, Y 2009, ‘Heterogeneous photocatalyst materials for water splitting’,Chemical Society of Reviews, vol. 38, no. 1, pp. 253-278.

Tseng, YH & Kuo, CH 2011, ‘Photocatalytic degradation of dye and NOx using visible light-responsive carbon containing TiO2’, Catalysis Today, Vol. 174, no. 1, pp. 114-120.

Ismaila, AA Geioushya, RA Bouzid, H AlSayari, SA Al-Hajry, A & Bahnemann, DW 2013, ‘TiO2 decoration of graphene layers for highly efficient photocatalyst: impact of calcination at different gas atmosphere on photocatalytic efficiency’, Applied Catalysis B: Environmental, vol. 129, pp. 129-132.

Gupta, VK Jain, R Mittal, A Saleh, TA Nayak, A Agarwal, S & Sikarwar, S 2012, ‘Photocatalytic degradation of toxic dye amaranth on TiO2/UV in aqueous

suspensions’, Materials Science and Engineering, vol. 32, no. 1, pp. 12-17.

Abo-Farha, SA 2010, ‘Photocatalytic degradation of monoazo and diazo dyes in

wastewater on nanometer-sized TiO2’, Journal of American Science, vol. 6, no. 11,130-142.

Devi, LG & Kumar, SG 2011, ‘Influence of physicochemical-electronic properties of transition metal ion doped polycrystalline titania on the photocatalytic degradation of Indigo Carmine and 4- nitrophenol under UV/solar light’, Applied Surface Science, vol. 257, no. 7, pp. 2779-2790.

Hoffmann, MR Martin, ST Choi, W & Bahnemann, DW 1995, ‘Environmental applications of semiconductor photocatalysis’, Chemical Reviews, vol. 95, no. 1, pp. 69-96.

Tang, WZ & Huang, CP 1995, ‘Photocatalyzed oxidation pathways of 2,4-dichlorophenol by CdS in basic and acidic aqueous-solutions’, Water Research, vol. 29, no. 2, pp. 745-756.

Sun, M Li, DZ Li, WJ Chen, Y Chen, Z He, Y & Fu, X 2008, ‘New Photocatalyst, Sb2S3 for degradation of methyl orange under visible - light irradiation’, Journal of Physical Chemistry C, vol. 112, no. 46, pp. 18076-18071.

Kormann, C Bahnemann, DW & Hoffmann MR 1988, ‘Photocatalytic production of H2O2 and organic peroxides in aqueous suspensions of TiO2, ZnO and desert sand’, Environmental Science and Technology, vol. 22, pp. 798–806.


Refbacks

  • There are currently no refbacks.