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Synthesis of Biodiesel fuel additive from Glycerol using Cationic ion exchange resin- A review

Dheer A. Rambhia, Sravanthi Veluturla, Archna Narula

Abstract


With the alarming increasing of oil consumption and the number of automotives being instilled, there has been immense research taking place to find a sustainable fuel to replace the current fossil fuels and also not render the current automotives obsolete. The current favorable solution to this is Biodiesel which can be generated either from oil seeds or waste vegetable oils. The selectivity of this process is 90% and the byproduct as glycerol. The synthesis of fuel additive from glycerol can be achieved by various reactions such as acetylation ,etherification and ketalization. A ketalization of glycerol yields 2,2-dimethyl-1,3-dioxolane-4-methanol  seemed eye catching as Solketal is a fuel additive and can be used to enhance the combustibility of biodiesel produced onsite rather than forming products for another industry. Similarly the  acetylation of glycerol yields triacetin, which has a wide application as fuel additive. Heterogeneous catalyst prevents the tedious process of catalyst separation and regeneration. Cationic ion exchange resins maintain their negative charge and attracting the positive charges of the reactant to propagate the reaction. For scaling up the production of fuel additive from glycerol demands the understanding of kinetics. Hence this paper discusses about the the kinetic studies undertaken and the various kinetic models developed for the production of fuel additives. The understanding of various kinetics enables us to know which reaction is favourable at particular conditions. Understanding the kinetics of the suitable reaction for the available conditions helps in efficient setting up of the process.

Keywords: Biodiesel, Glycerol, Cationic ion exchange resins,  Fuel additive,Kinetics.


Keywords


Biodiesel, Glycerol, Cationic ion exchange resins, Fuel additive,Kinetics.

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References


C. Huntingford and L. M. Mercado, “High chance that current atmospheric greenhouse concentrations commit to warmings greater than 1.5 °C over land,” Scientific Reports, vol. 6, no. 1, Sep. 2016.

A. Popp et al., “Land-use futures in the shared socio-economic pathways,” Global Environmental Change, vol. 42, pp. 331–345, Jan. 2017.

I. Mignon and A. Rüdinger, “The impact of systemic factors on the deployment of cooperative projects within renewable electricity production – An international comparison,” Renewable and Sustainable Energy Reviews, vol. 65, pp. 478–488, Nov. 2016.

S. H. Yoon and C. S. Lee, “Experimental investigation on the combustion and exhaust emission characteristics of biogas–biodiesel dual-fuel combustion in a CI engine,” Fuel Processing Technology, vol. 92, no. 5, pp. 992–1000, May 2011.

Air Quality Monitoring and Forecasting. MDPI AG - Multidisciplinary Digital Publishing Institute, 2018.

S. T. Keera, S. M. El Sabagh, and A. R. Taman, “Transesterification of vegetable oil to biodiesel fuel using alkaline catalyst,” Fuel, vol. 90, no. 1, pp. 42–47, Jan. 2011.

M. R. Avhad and J. M. Marchetti, “A review on recent advancement in catalytic materials for biodiesel production,” Renewable and Sustainable Energy Reviews, vol. 50, pp. 696–718, Oct. 2015.

M. R. Nanda, Z. Yuan, W. Qin, H. S. Ghaziaskar, M.-A. Poirier, and C. C. Xu, “Thermodynamic and kinetic studies of a catalytic process to convert glycerol into solketal as an oxygenated fuel additive,” Fuel, vol. 117, pp. 470–477, Jan. 2014.

P. Mukhopadhyay and R. Chakraborty, “Effects of Bioglycerol Based Fuel Additives on Diesel Fuel Property, Engine Performance and Emission Quality: A Review,” Energy Procedia, vol. 79, pp. 671–676, Nov. 2015.

R. Rodrigues, D. Mandelli, N. S. Gonçalves, P. P. Pescarmona, and W. A. Carvalho, “Acetalization of acetone with glycerol catalyzed by niobium-aluminum mixed oxides synthesized by a sol–gel process,” Journal of Molecular Catalysis A: Chemical, vol. 422, pp. 122–130, Oct. 2016.

E. Nowicka et al., “In situ spectroscopic investigation of oxidative dehydrogenation and disproportionation of benzyl alcohol,” Physical Chemistry Chemical Physics, vol. 15, no. 29, p. 12147, 2013.

N. N. Ezhova et al., “Glycerol carboxylation to glycerol carbonate in the presence of rhodium complexes with phosphine ligands,” Petroleum Chemistry, vol. 52, no. 2, pp. 91–96, Mar. 2012.

N. Simone, W. A. Carvalho, D. Mandelli, and R. Ryoo, “Nanostructured MFI-type zeolites as catalysts in glycerol etherification with tert -butyl alcohol,” Journal of Molecular Catalysis A: Chemical, vol. 422, pp. 115–121, Oct. 2016.

B. Mallesham, B. Govinda Rao, and B. M. Reddy, “Production of biofuel additives by esterification and acetalization of bioglycerol,” Comptes Rendus Chimie, vol. 19, no. 10, pp. 1194–1202, Oct. 2016.

L. Li, T. I. Korányi, B. F. Sels, and P. P. Pescarmona, “Highly-efficient conversion of glycerol to solketal over heterogeneous Lewis acid catalysts,” Green Chemistry, vol. 14, no. 6, p. 1611, 2012.

L. Zhou, T.-H. Nguyen, and A. A. Adesina, “The acetylation of glycerol over amberlyst-15: Kinetic and product distribution,” Fuel Processing Technology, vol. 104, pp. 310–318, Dec. 2012.

P. Hoo and A. Z. Abdullah, “Kinetics Modeling and Mechanism Study for Selective Esterification of Glycerol with Lauric Acid Using 12-Tungstophosphoric Acid Post-Impregnated SBA-15,” Industrial & Engineering Chemistry Research, vol. 54, no. 32, pp. 7852–7858, Aug. 2015.

E. G. Derouane, Ed., Catalysts for Fine Chemical Synthesis: Microporous and Mesoporous Solid Catalysts. Chichester, UK: John Wiley & Sons, Ltd, 2006.

F. G. Heineken, H. M. Tsuchiya, and R. Aris, “On the mathematical status of the pseudo-steady state hypothesis of biochemical kinetics,” Mathematical Biosciences, vol. 1, no. 1, pp. 95–113, Mar. 1967.

D. Wang, “Experimental Conditions for Valid Langmuir-Hinshelwood Kinetics,” Chinese Journal of Catalysis, vol. 31, no. 8, pp. 972–978, Aug. 2010.

E.O. Akbay and M. R. Altıokka, “Kinetics of esterification of acetic acid with n-amyl alcohol in the presence of Amberlyst-36,” Applied Catalysis A: General, vol. 396, no. 1–2, pp. 14–19, Apr. 2011.

J. Liu, B. Yang, and C. Yi, “Kinetic Study of Glycerol Etherification with Isobutene,” Industrial & Engineering Chemistry Research, vol. 52, no. 10, pp. 3742–3751, Mar. 2013.

R. P. V. Faria, C. S. M. Pereira, V. M. T. M. Silva, J. M. Loureiro, and A. E. Rodrigues, “Glycerol Valorization as Biofuel: Thermodynamic and Kinetic Study of the Acetalization of Glycerol with Acetaldehyde,” Industrial & Engineering Chemistry Research, vol. 52, no. 4, pp. 1538–1547, Jan. 2013.

I. Agirre et al., “Glycerol acetals, kinetic study of the reaction between glycerol and formaldehyde,” Biomass and Bioenergy, vol. 35, no. 8, pp. 3636–3642, Aug. 2011.




DOI: https://doi.org/10.37591/jocc.v6i3.3434

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