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Corrosion Inhibition Effect of 1-(4-Methoxy-phenyl)-3-(5-phenyl-1,3,4-oxadiazol-2-yl) propan-1-one Inhibitor for Mild Steel in 1 M HCl Solution

Pruthviraj R.D.

Abstract


The environmental friendly 1-(4-Methoxy-phenyl)-3-(5-phenyl-1,3,4-oxadiazol-2-yl) propan-1-one (A1) inhibitor is synthesized and their corrosion inhibition for Mild Steel in a 1 M HCl solution was studied using weight loss methods, electrochemical measurements, and the surface morphology of mild steel with and without inhibitor were studied using scanning electron microscopy (SEM) analysis. As the concentration of the inhibitor was increased the inhibition efficacy of 1-(4-Methoxy-phenyl)-3-(5-phenyl-1, 3, 4-oxadiazol-2-yl) propan-1-one was also enhanced and on the other it decreased with the increase in temperature. The corrosion inhibition efficiency of 1-(4-Methoxy-phenyl)-3-(5-phenyl-1, 3,4-oxadiazol-2-yl) propan-1-one was outstanding, according to results from potentiodynamic polarisation and EIS. Morphology observation revealed that the Mild Steel was greatly protected by these 1-(4-Methoxy-phenyl)-3-(5-phenyl-1,3,4-oxadiazol-2-yl) propan-1-one inhibitor.


Keywords


Mild Steel; potentiodynamic polarization; EIS, corrosion inhibition

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References


Dabalà, M.; Ramous, E.; Magrini, M. Corrosion resistance of cerium-based chemical conversion coatings on AA5083 aluminium alloy. Mater. Corros. 2004; 55(5): 381–386.

Musa, A.Y.; Kadhum, A.A.H.; Mohamad, A.B.; et.al. On the inhibition of mild steel corrosion by 4-amino-5-phenyl-4H-1,2,4-trizole-3-thiol. Corros. Sci. 2010; 52: 526–533.

Rosliza, R.; Nik, W.B.W.; Izman, S.; et.al. Anti-corrosive properties of natural honey on Al–Mg–Si alloy in seawater. Curr. Appl. Phys. 2010; 10(3): 923–929.

Hill, J.A.; Markley, T.; Forsyth, M.; et.al. Corrosion inhibition of 7000 series aluminium alloys with cerium diphenyl phosphate. J. Alloy. Compd. 2011; 509(5): 1683–1690.

Rosliza, R.; Nik, W.B.W.; Senin, H.B. The effect of inhibitor on the corrosion of aluminum alloys in acidic solutions. Mater. Chem. Phys. 2008; 107(2-3): 281–288.

Gudic´, S.; Vrsalovic´, L.; Kliškic´, M.; et.al. Corrosion Inhibition of AA 5052 Aluminium Alloy in NaCl Solution by Different Types of Honey. Int. J. Electrochem. Sci. 2016; 11: 998–1011.

Oguzie, E.E.; Onuoha, G.N.; Ejike, E.N. Effect of gongronema latifolium extract on aluminium corrosion in acidic and alkaline media. Pigment Resin Technol. 2007; 36(1): 44–49.

Al-Turkustani, A.M.; Arab, S.T.; Al-Dahiri, R.H. Aloe plant extract as environmentally friendly inhibitor on the corrosion of aluminum in hydrochloric acid in absence and presence of iodide ions. Mod. Appl. Sci. 2010; 4(5): 105–124.

Li, J.; Hurley, B.; Buchheit, R. Microelectrochemical characterization of the effect of rare earth inhibitors on the localized corrosion of AA2024-T3. J. Electrochem. Soc. 2015; 162: C563–C571.

Ilevbare, G.O.; Scully, J.R. Mass-transport-limited oxygen reduction reaction on AA2024-T3 and selected intermetallic compounds in chromate-containing solutions. Corrosion. 2001; 57(2): 134–152.

Yurt, A.; Ulutas, S.; Dal, H. Electrochemical and theoretical investigation on the corrosion of aluminium in acidic solution containing some Schiff bases. Appl. Surf. Sci. 2006; 253(2): 919–925.

Maayta, A.K.; Al-Rawashdeh, N.A.F. Inhibition of acidic corrosion of pure aluminum by some organic compounds. Corros. Sci. 2004; 46(5): 1129–1140.

Khaled, K.F. Electrochemical investigation and modeling of corrosion inhibition of aluminum in molar nitric acid using some sulphur-containing amines. Corros. Sci. 2010; 52(9): 2905–2916.

Zhang, Q.B.; Hua, Y.X. Corrosion inhibition of aluminum in hydrochloric acid solution by alkylimidazolium ionic liquids. Mater. Chem. Phys. 2010; 119(1-2): 57–64.

Hachelef, H.; Benmoussat, A.; Khelifa, A.; et.al. Study of corrosion inhibition by Electrochemical Impedance Spectroscopy method of 5083 Mild Steelin 1 M HCl solution containing propolis extract. J. Mater. Environ. Sci. 2016; 7: 1751–1758.

Zhao, Q.; Tang, T.; Dang, P.; et.al. Preparation and analysis of complex barrier layer of heterocyclic and long-chain organosilane on copper alloy surface. Metals. 2016; 6(7): 162.

Yoo, S.H.; Kim, Y.W.; Chung, K.; et.al. Corrosion Inhibition Properties of Triazine Derivatives Containing Carboxylic Acid and Amine Groups in 1 M HCl Solution. Ind. Eng. Chem. Res. 2013; 52(32): 10880–10889.

Li, Y.; Wang, D.; Zhang, H.; et.al. Study on triazinethiol electropolymerized films prepared by cyclic voltammetry and galvanostatic on copper alloy surface. Int. J. Electrochem. Sci. 2011; 6: 4404–4410.

Wang, F.; Liu, J.; Li, Y.; et.al. Complex barrier layer of triazinedithoil prepared by electrodeposition and initiated polymerization on Mild Steeltowards corrosion protection. Int. J. Electrochem. Sci. 2012; 7: 3672–3680.

Shalabi, K.; Abdallah, Y.M.; Fouda, A.S. Corrosion inhibition of aluminum in 0.5 M HCl solutions containing phenyl sulfonylacetophenoneazo derivatives. Res. Chem. Intermed. 2014; 41(7): 4687–4711.

Obi-Egbedi, N.O.; Obot, I.B. Inhibitive properties, thermodynamic and quantum chemical studies of alloxazine on mild steel corrosion in H2SO4. Corros. Sci. 2011; 53(1): 263–275.

Eddy, N.O.; Momoh-Yahaya, H.; Oguzie, E.E. Theoretical and experimental studies on the corrosion inhibition potentials of some purines for aluminum in 0.1 M HCl. J. Adv. Res. 2015; 6(2): 203–217.

Halambek, J.; Jukic´, M.; Berkovic´, K.; et.al. Investigation of novel heterocyclic compounds as inhibitors of Al-3Mg alloy corrosion in hydrochloric acid solutions. Int. J. Electrochem. Sci. 2012; 7: 1580–1601.

Schorr, M.; Yahalom, J. The significance of the energy of activation for the dissolution reaction of metal in acids. Corros. Sci. 1972; 12(11): 867–868.

Kabir, K.B.; Mahmud, I. Study of erosion-corrosion of stainless steel, brass and aluminum by open circuit potential measurements. J. Chem. Eng. 2010; 25: 13–17.

Abiola, O.K.; Otaigbe, J.O.E. Effect of common water contaminants on the corrosion of aluminium alloys in ethylene glycol–water solution. Corros. Sci. 2008; 50(1): 242–247.

Maghraby, A.A.E. Corrosion inhibition of aluminum in hydrochloric acid solution using potassium iodate inhibitor. Open Corros. J. 2009; 2: 189–196.

Ladha, D.G.; Wadhwani, P.M.; Kumar, S.; et.al. Evaluation of corrosion inhibitive properties of trigonellafoenum-graecum for pure aluminium in hydrochloric acid. J. Mater. Environ. Sci. 2015; 6(5): 1200–1209.

S¸ afak, S.; Duran, B.; Yurt, A.; et.al. Schiff bases as corrosion inhibitor for aluminium in HCl solution. Corros. Sci. 2012; 54: 251–259.

Oguzie, E.E.; Li, Y.; Wang, F.H. Corrosion inhibition and adsorption behavior of methionine on mild steel in sulfuric acid and synergistic effect of iodide ion. J. Colloid Interface Sci. 2007; 310(1): 90–98.

Herrag, L.; Hammouti, B.; Elkadiri, S.; et.al. Adsorption properties and inhibition of mild steel corrosion in hydrochloric solution by some newly synthesized diamine derivatives: Experimental and theoretical investigations. Corros. Sci. 2010; 52(9): 3042–3051.

Fouda, A.S.; Mohamed, F.S.; El-Sherbeni, M.W. Corrosion inhibition of aluminum–silicon alloy in hydrochloric acid solutions using carbamidic thioanhydride derivatives. J. Bio- Tribo-Corros. 2016; 2: 1–16.

Kathirvel, K.; Thirumalairaj, B.; Jaganathan, M. Quantum chemical studies on the corrosion inhibition of mild steel by piperidin-4-one derivatives in 1 M H3PO4. Open J. Met. 2014; 4(4): 73–85.


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