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Conductive Organic Polymer Based Inorganic-Organic Hybrid Composite: Synthesis and Characterization

Anita Devi, Honey Sharma, Mukesh Kumar

Abstract


Inorganic organic (IO) hybrids where inserted conducting organic polymer (COP) imprints their polymeric nature onto the hybrid material are one of the most promising candidates for solving many technological problems of modern technocratic society. The Inorganic-organic hybrid material of para toluidine (organic) & mercuric chloride (inorganic) was synthesized by using “instant-heating and slow-cooling” technique. Some light orange coloured plate-like crystals were obtained. XRD pattern of the grown crystal were analysed which shows that crystal has been grown into monoclinic crystal system in which a ≠ b ≠ c [10.061(4) Å ≠ 4.317(2) Å ≠ 12.987(5) Å] & α=γ= 90o≠ β [α = γ = 90o, β=104.322(7) o] and belongs to space group p21.Analysis of secondary interactions shows that such material has potential application in opto electronics.


Keywords


Conducting organic polymers, inorganic-organic hybrids, secondary interactions, slow cooling, optoelectronic devices, non covalent weak interactions, hydrogen bond.

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References


G. Kickelbick. “Hybrid Materials- Past, Present and Future”. Hybrid Materials. Vol: 1, Issue: 1, pp: 39-51, 2014.

Z. Kuang Tan, R.Saberi, H. Richard et al. “Bright Light Emitting Diode Based on Organometal Halide Perovskite”. Nature Nanotechnology, Vol:9, issue:9, pp:687-692,2014.

Z. Yuan, C. Zhou, Y. Tian et al. “One Dimensional Organic Lead Halide Perovskite with Efficient Bluish White Light Emission”. Nature Communication. Vol: 8, pp: 14051, 2017.

B. Hwang, J. Sik Lee. “Recent Advances in Memory Devices with Hybrid Materials”. Advanced Electronics Materials.Vol:5, Issue: 1, pp: 1-22, 2018.

Z. Kuang Tan, R. Saberi, H. Richard et al. “Bright Light Emitting Diode Based on Organometal Halide Perovskite”. Nature Nanotechnology. 2014; Vol: 9, Issue9, pp: 687-692, 2014.

D. Jasrotia, S. K. Verma, B. Sridhar et al. “3-D-2D Lattice Dimensionality, Optical Eg and PL Energy Variation Due To Organic Variant in Two [ZnCl4]2- Based Hybrid Materials”. Material Chemistry and Physics, Vol: 207, pp: 98-104, 2018.

B. Hwang, J.S. Lee. “Recent Advances in Memory Devices with Hybrid Materials”. Advanced Electronics Materials, Vol:5, Issue:1, pp:1800519(1-22), 2018.

C.Gu, J. S. Lee. “Flexible Hybrid Organic Inorganic Perovskite Memory”. ACS Nano. 2016; Vol: 10, Issue: 5, pp: 5413-5418, 2016.

G.R. Raju. “Crystal Engineering: A holistic View”. Angewandte Chemie. Vol: 46, pp: 8342-8356, 2007.

P.G.Romero. “Hybrid Organic Inorganic Materials-In Search Of Synergic Activity”. Advanced Materials. Vol: 13, Issue: 3, pp: 163-172. 2001.

S. K. Verma, D. Jasrotia, B. Singh et al. “Structure Stability Relationship In [CdBr4] series of Metal organic Material”. International Journal of Advance Research in Science and Engineering.Vol:7, Issue: 4, pp: 1587-1596. 2018.

Aronwalsh. “Principles of Chemical Bonding and Band Gap Engineering in Organic Inorganic Halide Perovskite”. Journal of Physical Chemistry C. Vol: 119, Issue: 11, pp: 5755-5760, 2015.

A.Boultif and D. Lour. “Indexing of powder diffraction Pattern”. Journal of Applied Crystallography.Vol: 24, pp: 987-993, 1991.

P. G. Romero and C. Sanchez. “Hybrid materials functional properties from Maya blue to 21st century materials”. New Journal of Chemistry. Vol: 29, pp: 57-58.2005.

B. Singh and D. Jasrotia. Futuristic Research On Weak Forces In Inorganic –Organic Hybrids: Weak Forces In organic Inorganic Hybrids. Educreation Publishing. Dwarka, New Delhi-110075. 2018. ISBN-978-81-936181-03.

P. R. Vardawaj, A. Vardawaj and M. Marques. “Halogen Bonding: A Halogen Centered Non- Covalent Interaction Yet To Be Understood”. Inorganics. Vol: 7, issue: 3, pp: 40. 2019.

B. Singh, A. Thakur, M. Kumar et al. “Structure and Optical Properties of Inorganic-Organic Hybrid material Of Acetanilide Tetrachloromercurate”. Journal of Material Science: Material in Electronics. Vol: 28, Issue: 14, pp: 10007-100011. 2017.

M. Kumar, B. Singh et al. “Bang of Hydrogen Bonding on Covalent Bond in HgX Based (X=Cl, Br, I) Inorganic Organic Hybrid Material”. Indian Journal of Applied Research. Vol: 5,Issue:9, pp:651-652, 2015.

P. R. Varadvaj, A. Varadvaj, K. Yamashita et al. “Significance Of Hydrogen Bonding And Other Non Covalent Interaction In Determining Octahedral Tilting In CH3NH3PbI3 Hybrid Organic Inorganic Halide Perovskite Solar Cell Semiconductor”. Scientific Reports. 2019.




DOI: https://doi.org/10.37591/jopc.v8i1.3769

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