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Geopolymerization: A Review on Physico-chemical Factors Influence to the Reaction Process
Abstract
A geopolymer is one of materials belonging to an inorganic polymer group based on alumino-silicate structural networks. The material is a product of reactions among the activated alumino silicate resources and solutions of alkaline activators in various conditions. There have been many investigations conducted to produce geopolymer using different raw materials and methods. The chemical factors have a decisive role in the reaction process and the formation of the geopolymeric structural networks. The physical factors significantly influenceon engineering properties, microstructural characteristicsas well as the effectiveness of the reactions. This study is a review on evaluation of relationships among physico-chemical factors in the reaction process. In which, the chemical factors were considered both the alumino-silicate raw materials and alkaline activators. The physical factors were evaluated on the various conditions known as mixing time, curing time and curing temperature.
Keywords
References
Davidovits, J., Geopolymer chemistry and application (5th edition). Institut Géopolymère – France, 2020.
Xu, H., Deventer, J.S.J.V., Effect of Source Materials on Geopolymerization,Ind. Eng. Chem. Res., 2003, 42, 1698-1706.
Xu, H. and Deventer, J.S.J.V., The geopolymerisation of alumino-silicate minerals. International journal of mineral proceesing, 2000, 59, 247-266.
Jaarsveld, J.G.S.V. and Deventer, J.S.J.V., The effect of metal contaminants on the formation and properties of waste-based geopolymers. Cement and Concrete Research, 1999, 29, 1189-1200.
Provis, J.L. and van Deventer, J.S.J., Alkali Activated Materials: State of the art report. RILEM-TC244 AAM. Springer Dordrecht Heidelberg New York London, 2014.
Yip, C.K., Lukey, G.C., Provis, J.L., and van Deventer, J.S.J., Effect of calcium silicate sources on geopolymerisation. Cement and Concrete Research, 2008, 38, 554-564.
Zhang, G., and He, J., Geopolymerization of red mud and rice husk ash and potentials of the resulting geopolymeric products for civil infrastructure applications. Developments in Strategic Materials and Computational Design II, The American Ceramic Society, 2011,
-52.
Nguyen, H.T., Synthesis and Characteristics of Inorganic Polymer Materials Geopolymerized from Ash of Brickyard, Materials Science Forum, 2019, 961, 45-50.
Komnitsas, K. and Zaharaki, D., Geopolymerisation: A review and prospects for the minerals industry. Min. Eng.,2007, 20, 1261-1277.
Giannopoulou, I. and Panias, D., Structure, Design and Applications of Geopolymeric Materials. 3rd International Conference – Deformation Processing and Structure of Materials, September 20, 22nd, 2007, Belgrade, Serbia.
Nguyen H.T., Evaluation on Formation of Aluminosilicate Network in Ternary-Blended Geopolymer Using Infrared Spectroscopy,Solid State Phenomena 2019, 296, 99–104.
Davidovits, J.,30 Years of Successes and Failures in Geopolymer Applications. Market Trends and Potential Breakthroughs. Geopolymer 2002 Conference, October 28-29, 2002, Melbourne, Australia, 1- 16.
Petermann, J. C., Saeed, A., and Hammons, M.I., Aklali-Activated Geopolymers: A Literature Review. Distribution A. Approved for public release; distribution unlimited. 88ABW-2012-2030, 6 February 2012.
Le, V.Q., Do, Q.M., Hoang, M.D., Dang, T.P., Bui, T.H., Nguyen, H.T., Evaluation on Roles of Activated Silicon and Aluminum Oxides for Formation of Geopolymer from Red Mud and Silica Fume, Key Engineering Materials, 2018, 777, 513-517.
Kumar, A. and Kumar, S., Development of paving blocks from synergistic use of red mud and fly ash using geopolymerization, Construction and Building Materials, 2013 865-871.
Barbosa, V. F.F., MacKenzie, K. J.D., Thaumaturgo, C., Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers. International Journal of Inorganic Materials, 2000, 2, 309-317.
Ferraris, C.F., Hackley, V.A., Aviles, A.I., and Buchanan, C.A.Jr., Analysis of the ASTM Round-Robin Test on Particle Size Distribution of Portland Cement: Phase I. National Institute of Standards and Technology Internal Report 6883, U.S. Department of Commerce Technology Administration, 2002.
ASTM C115-96a, Standard Test Method for Fineness of Portland cement by Turbidimeter. American Society for Testing and Materials. Philadelphia June 2000. Sec.4, Vol. 04.01.
Allahverdi, A., Mehrpour, K., Kani,E. N.,Taffanpozzolan – based geopolymer cement. IUST International Journal of Engineering Science, 2008, 19, 3, 1-5.
Le, V.Q., Do, Q.M., Hoang, M.D., Pham, V.T.H.Q., Bui, T.H., Nguyen, H.T., Effect of Alkaline Activators to Engineering Properties of Geopolymer-Based Materials Synthesized from Red Mud, Key Engineering Materials, 2018 777,
-512.
Do, Q.M., Ngo, P.M., Nguyen, H.T., Characteristics of a Fly Ash-Based Geopolymer Cured in Microwave Oven. Key Engineering Materials, 2020, 850, 63–69.
Monnin, C. and Dubois, M., Thermodynamics of the LiOH+H2O system. J. Chem. Eng,2005, 50 (4),
-1113.
Gurvich, L.V., Bergman, G.A., Gorokhov, L.N., Iorish, V.S., Leonidov, V.Y., and Yungman, V.S., Thermodynamic properties of alkali metal hydroxides. Part 2. Potassium, rubidium, and cesium hydroxides. J. Phys. Chem. Ref., 1997,26 (4) 1031-1110.
Simonson, J.M., Mesmer, R.E., Rogers, P.S.Z., The enthalpy of dilution and apparent molar heat capacity of NaOH (aq) to 523 K and 40 MPa,J. Chem. Thermodyn,1989, 21, 561-584.
Cundy, C.S. and Cox, P.A., The hydrothermal synthesis of zeolites: Precursors, intermediates and reaction mechanism. Microporous and Mesoporous Materials,2005, 82, 1-78.
Santra, A.K. and Luke, K., Zeolite compositions having enhanced compressive strength. US 7,048,053 B2, 2006.
Gartner, E., Industrially interesting approaches to “low-CO2 ” cements. Cem.Concr. Res,2004, 34 (9) 1489-1498.
Do, Q.M., Bui, T.H., Nguyen, H.T., Effects of Seawater Content in Alkaline Activators to Engineering Properties of Fly Ash-Based Geopolymer Concrete, Solid State Phenomena, 2019, 296,
-111..
Le, V.Q., Nguyen, H.T., Bui, T.H., Pham, V.T.H.Q., Do, Q.M., Hoang, M.D., Leaching behavior and immobilization of heavy metals in geopolymer synthesized from red mud and fly ash,Key Engineering Materials, 2018, 777,
-522.
Hardjito, D. and Rangan, B.V., Development fly ash – based geopolymer concrete: progress and research needs. 2nd Asian concrete federation conference – Bali, Indonesia, November 20-21, 2006.
Khale, D. and Chaudhary, R., Mechanism of geopolymerization and factors influencing its development: a review. Journal ofMaterials Science,2007, 42, 729-746.
MacKenzie, K.J.D., Komphanchai, S., and Vagana, R., Formation of inorganic polymers (geopolymers) from 2:1 layer lattice aluminosilicates. Journal of the European Ceramic Society,2008, 28,
-181.
ASTM C109/109M,Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-in. or [50-mm] Cube Specimens). American Society for Testing and Materials. Philadelphia June 2000. Sec.4, Vol. 04.01.
Yunsheng, Z., Wei, S., Qianli, C., and Lin, C., Synthesis and heavy metal immobilization behaviors of slag based geopolymer. Journal of Hazardous Materials, 2006, 143, 206-213.
Nguyen, H.T., Le, T.N, Pham, V.T.H.Q., Dang, T.P., Dao, T.K. Nguyen, V.P., Development of heat resistant geopolymer-based materials from red mud and rice husk ash, AIP Conference Proceedings, 2018, 1954, 040005.
Nguyen, H.T., Nguyen, N.H., Pham, V.T.H.Q., Nguyen, N.K.T., Tran, V.T.A., Pham, T.K., Engineering properties of lightweight geopolymer synthesized from coal bottom ash and rice husk ash, AIP Conference Proceedings, 2018, 1954, 040009.
DOI: https://doi.org/10.37591/jopc.v8i3.4349
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