A Parametric Study of Methylene Blue Adsorption Using Low-cost Adsorbent
DOI:
https://doi.org/10.37591/jotcsta.v10i3.7889Keywords:
Spanish Cherry Fruit Peel, Low-Cost Adsorbent, Methylene Blue Dye, AdsorptionAbstract
This research focused on the adsorptive capacity of activated carbonaceous substance made from the peel of Spanish cherries to remove methylene blue dye from wastewater. Through batch adsorption tests, the impact of several variables on the percentage of dye removal was examined. These variables included adsorbent preparation temperature, adsorbent dosages, initial concentration of dye solution, process time, pH of dye solution, and operation temperature. It was found that using 1 g/100 ml adsorbent (carbonization temperature 650°C) at pH 7 and 30°C for 1 hour, maximum dye removal of 81.5% was achieved. The moisture content and the BET surface area of this low-cost adsorbent were found to be 9.22% and 380 m2/gm, respectively. The Freundlich adsorption and Langmuir adsorption isotherm models were used to verify the experimental findings. The maximum adsorption capacity for monolayer coverage was determined to be 114.94 mg/gm, according to the correlation coefficient (R2) values, which showed that the model that best matched the experimental data was the Langmuir adsorption isotherm. The experimental data were also shown to closely reflect the pseudo-second-order kinetics using adsorption kinetic investigations. According to the findings, methylene blue can be effectively removed from wastewater by using the peel of Spanish cherry fruits as an adsorbent.References
K. L. Wasewar, S. Singh, S. K. Kansal, Process Intensification of Treatment of Inorganic Water Pollutants, Inorganic Pollutants in Water, 2020, 245–271
Y. Wang, L. Zhu, H. Jiang, F. Hu, X. Shen, Application of Longan Shell as Non-Conventional Low-Cost Adsorbent for the Removal of Cationic Dye from Aqueous Solution, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 159, 254–261.
D. A. Yaseen & M. Scholz, Textile Dye Wastewater Characteristics and Constituents of Synthetic Effluents: A Critical Review, International Journal of Environmental Science and Technology, (2019) Volume 16, 1193–1226
A. S. Yusuff, O. A. Ajayi, L.T. Popoola, Application of Taguchi Design Approach to Parametric Optimization of Adsorption of Crystal Violet Dye by Activated Carbon from Poultry Litter, Scientific African, Volume 13, September 2021, e00850
S.A. Umoren, U. J. Etim, A. U. Israel, Adsorption of Methylene Blue from Industrial Effluent Using Poly (Vinyl Alcohol), J. Mater. Environ. Sci., 4 (1) (2013) 75–86
L. Liu, B. Zhang, Y. Zhang, Y. He, L. Huang, S. Tan, and X. Cai, Simultaneous Removal of Cationic and Anionic Dyes from Environmental Water Using Montmorillonite-Pillared Graphene Oxide, J. Chem. Eng. Data 2015, 60, 5, 1270–1278
G. Mezohegyi, F. P. van der Zee, J. Font, A. Fortuny, and A. Fabregat, Towards Advanced Aqueous
Dye Removal Processes: A Short Review on The Versatile Role of Activated Carbon, Environ.
Manage., 2012, 102, 148–164.
H. Trevino-Cordero, L. G. Juarez-Aguilar, D. I. Mendoza-Castillo, V. Hernandez-Montoya, A.
Bonilla-Petriciolet and M. A. Montes-Moran, Synthesis and Adsorption Properties of Activated
Carbons from Biomass of Prunus Domestica and Jacaranda Mimosifolia for The Removal of Heavy
Metals and Dyes from Water, Ind. Crop Prod., 2013, 42, 315–323
A. S. Yusuff, A. O. Gbadamosi & J. F. Ngochindo, Synthesis and Characterization of Anthill
Eggshell Composite Adsorbent for Removal of Hexavalent Chromium from Aqueous Solution,
Environmental Science and Pollution Research, (2018), volume 25, 19143–19154
G. Z. Kyzas, N. K. Lazaridis and A. C. Mitropoulos, Removal of Dyes from Aqueous Solutions
with Untreated Coffee Residues as Potential Low-Cost Adsorbents: Equilibrium, Reuse and
Thermodynamic Approach, Chem. Eng. J., 2012, 189–190, 148–159.
A. Debrassi, A. F. Correa, T. Baccarin, N. Nedelko, A. Slawska-Waniewska, K. Sobczak, P.
Dłużewski, J. M. Greneche and C. A. Rodrigues, Removal of Cationic Dyes from Aqueous
Solutions Using N-Benzyl-O-Carboxymethyl chitosan Magnetic Nanoparticles, Chem. Eng. J.,
, 183, 284–293
S. D. Gisi, G. Lofrano, M. Grassi, M. Notarnicola, Characteristics and Adsorption Capacities of
Low-Cost Sorbents for Wastewater Treatment: A Review, Sustainable Materials and Technologies
(2016) 10–40
S. Kumar, V. Gunasekar and V. Ponnusami, Removal of Methylene Blue from Aqueous Effluent
Using Fixed Bed of Ground Nut Shell Powder, Journal of Chemistry Volume 2013, Article ID
, 5
J. Rashid, F. Tehreem, A. Rehman, R. Kumar, Synthesis Using Natural Functionalization of
Activated Carbon from Pumpkin Peels for Decolourization of Aqueous Methylene Blue, Science
of The Total Environment, Volume 671, 25 June 2019,369-376
L.Yan, L. Sizhong, Preparation of Hierarchically Interconnected Porous Banana Peel Activated
Carbon for Methylene Blue Adsorption, J. Wuhan Univ. Technol.- Materials (2019) Sci. Ed. 34 (2),
–480.
S. Shakoor, A. Nasar, Adsorptive Treatment of Hazardous Methylene Blue Dye from Artificially
Contaminated Water Using Cucumis Sativus Peel Waste as A Low-Cost Adsorbent, Groundwater,
(2017), Sustain. Dev. 5, 152–159.
S. Robles, Nava, V. Nestor, C. Beltr, G. Guti, L. Medina, Olivas, Luque, Biosynthesized Zinc Oxide
Using Lycopersicon Esculentum Peel Extract for Methylene Blue Degradation, (2018), J. Mater.
Sci. Mater. Electron. 29 (5), 3722–3729.
A.H. Jawad, A.M. Kadhum, Y. Ngoh, Applicability of Dragon Fruit (Hylocereus Polyrhizus) Peels
as Low-Cost Bio-Sorbent for Adsorption of Methylene Blue from Aqueous Solution: Kinetics,
Equilibrium and Thermodynamics Studies, (2018), Desal. Water Treat. 109, 231–240.
S. Samarbaf, Y. T. Birgani, M. Yazdani, A. A. Babaei, A Comparative Removal of Two Dyes from
Aqueous Solution Using Modified Oak Waste Residues: Process Optimization Using Response
Surface Methodology, Journal of Industrial and Engineering Chemistry, (2019), Volume 73,67–77
I. Bencheikh, K. Azoulay, J. Mabrouk, S. El Hajjaji, A. Dahchour, A. Moufti, D. Dhiba, The
Adsorptive Removal of MB Using Chemically Treated Artichoke Leaves: Parametric, Kinetic,
Isotherm and Thermodynamic Study Scientific African, 9 (2020) e00509
B. T. Gemici, H. U. Ozel, H.B. Ozel, Removal of Methylene Blue onto Forest Wastes: Adsorption
Isotherms, Kinetics and Thermodynamic Analysis Environmental Technology &Innovation,
Volume 22, May 2021, 101501
I. Langmuir, The Constitution and Fundamental Properties of Solids and Liquids, J. Am. Chem.
Soc. 1916, 38, 2221−2295.
S. Shakoor, A. Nasar, Removal of Methylene Blue Dye from Artificially Contaminated Water
Using Citrus Limetta Peel Waste as A Very Low-Cost Adsorbent, Journal of the Taiwan Institute
of Chemical Engineers 000 (2016) 1–10
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